N-(2-Ferrocenylethylidene)-4-(trifluoromethyl)aniline
نویسنده
چکیده
The title compound, [Fe(C(5)H(5))(C(13)H(9)F(3)N)], was prepared by a condensation reaction from ferrocenylcarbaldehyde and 4-(trifluoro-meth-yl)aniline. The cyclo-penta-dienyl (Cp) rings are coplanar [dihedral angle = 1.4 (3)°] and the imine function is situated in the same plane. The aromatic substituent is bent out of the plane of the Cp ring to which the imine group is attached by 44.5 (4)°. The F atoms of the trifluoro-methyl substituent are disordered [occupancies 0.52 (2)/0.48 (2)].
منابع مشابه
Diethyl 2-{[2-(trifluoromethyl)anilino]methylidene}propanedioate
The title compound, C(15)H(16)F(3)NO(4), is an N-substituted derivative of ortho-trifluoro-methyl-aniline featuring a twofold Michael system. The least-squares planes defined by the atoms of the phenyl ring and the atoms of the Michael system enclose an angle of 15.52 (5)°. Apart from classical intra-molecular N-H⋯O and N-H⋯F hydrogen bonds, inter-molecular C-H⋯O contacts are observed, the latt...
متن کامل4-Methoxy-3-(trifluoromethyl)aniline
In title compound, C(8)H(8)F(3)NO, the meth-oxy group is inclined at 8.7 (4)° to the benzene ring plane. The crystal structure is stabilized by inter-molecular N-H⋯F, N-H⋯N and C-H⋯F hydrogen-bonding inter-actions.
متن کاملN-(4-Methylbenzyl)-3-nitroaniline
In the title compound, C(14)H(14)N(2)O(2), the angle between the mean plane of the N-methyl-3-nitro-aniline system (r.m.s. deviation = 0.0185 Å) and the p-tolyl unit is 89.79 (4)°. In the crystal, hydrogen-bonded chains running along [10-1] are generated by the linking of neighbouring mol-ecules via N-H⋯O and C-H⋯O hydrogen bonds involving the 3-nitro-aniline systems and forming R(2) (2)(8) mot...
متن کاملCrystal structure of bis(4-nitroaniline-κN 1)(5,10,15,20-tetraphenylporphyrinato-κ4 N)cobalt(III) chloride dichloromethane monosolvate
The reaction of [Co(III)(TPP)Cl] (TPP is the dianion of 5,10,15,20-tetra-phenyl-porphyrin) with an excess of 4-nitro-aniline in di-chloro-methane leads to the title compound, [Co(III)(C44H28N4)(C6H6N2O2)2]Cl·CH2Cl2. The Co(III) ion lies on an inversion centre and is octa-hedrally coordinated by two N atoms of the NH2 groups of the two 4-nitro-aniline trans-axial ligands and four pyrrole N atoms...
متن کاملSynthesis, Characterization and Application of Four Novel Electrochromic Materials Employing Nitrotriphenylamine Unit as the Acceptor and Different Thiophene Derivatives as the Donor
In this study, four novel donor–acceptor systems, 4-(2,3-dihydrothieno[3,4-b][1,4]dioxin5-yl)-N-(4-(2,3-dihydrothieno[3,4-b][1,4]dioxin-5-yl)phenyl)-N-(4-nitrophenyl)aniline (NETPA), 4-(4methoxythiophen-2-yl)-N-(4-(4-methoxythiophen-2-yl)phenyl)-N-(4-nitrophenyl)aniline (NMOTPA), 4-(4-methylthiophen-2-yl)-N-(4-(4-methylthiophen-2-yl)phenyl)-N-(4-nitrophenyl)aniline (NMTPA) and 4-nitro-N,N-bis(4...
متن کامل